STRUCTURE OF THE Cu(salen) MOLECULE CuO2N2C16H14 ACCORDING TO GAS-PHASE ELECTRON DIFFRACTION DATA AND QUANTUM CHEMICAL CALCULATIONS
N. I. Giricheva, G. V. Girichev, N. P. Kuzmina, Y. S. Medvedeva, A. Y. Rogachev
Keywords: structure, Schiff bases, CuO2N2C16H14, Cu(salen), electron diffraction, quantum chemical calculations
Pages: 58-65
Abstract
In the framework of synchronous gas-phase electron diffraction and mass spectrometry experiment, the saturated vapor of N,N'-ethylenebis(salicylaldiminate) copper(II) CuO2N2C16H14 is studied at a temperature T 574(5) K. It is found that evaporation is congruent and the saturated vapor consists of monomeric molecules. Electron diffraction data are proved to correspond to the geometric model for the CuO2N2C16H14 molecule of
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