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Chemistry for Sustainable Development

2007 year, number 2

Influence of Activation Method of Sorbents on Their Properties

Š. Jakabsky1, M. Lovas1, S. Hredzak1 and F. MacaŠek2
1Institute of Geotechnics of the Slovak Academy of Sciences,
Watsonova 45, 043 53 Košice (Slovakia)
E-mail: jakabsky@saske.sk
2Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University,
Mlynska dolina CH-1, Bratislava 842 15 (Slovakia)
Pages: 169-173

Abstract

The contribution describes chemical, physical and mineralogical properties of so-called Albanian (ore origin) leaching residuum from dumping ground of former Sered' Nickel Works (West Slovakia). The main mineral component of this residuum represents synthetic magnetite, which is known by its ability to sorb some substances. The changes in grain size and specific surface were studied as a function of grinding time and mill. The activation in ball mill during 25 min resulted in a two-fold increase in specific surface. Contrary to this fact, grinding in attritor led to a three-fold increase in specific surface already after 15min, i.e. from 1.31 to 3.86 m2/cm3.
For adsorption tests and following magnetic filtration the leaching residuum ground in the solution of K4Fe(CN)6 was applied. Obtained results point to the fact, that magnetic sorbent prepared in such a way and magnetic filtration enable substantial reduction of ion concentration of heavy metals such as copper, manganese and zinc.