Activity of Divinylsulphonyl- and Divinylsulphanyl- Tetrafluorobenzenes in Polymerizations
S. V. AMOSOVA, E. I. BIRYUKOVA, G. M. GAVRILOVA, S. A. ZHIVETYEVA and A. V. AFONIN
A. E. Favorskiy Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences,
Ul. Favorskogo 1, Irkutsk 664033 (Russia) E-mail: amosova@irioch.irk.ru
Pages: 583-587
Abstract
Quantitative and comparative analysis of the activity of 3,6-bis(vinylsulphonyl)-1,2,4,5-tetrafluorobenzene and 3,6-bis(vinylsulphonyl)-1,2,4,5-tetrafluorobenzene in radical copolymerizations with styrene has been carried out. 3,6-Bis(vinylsulphonyl)-1,2,4,5-tetrafluorobenzene possesses high reactivity in radical reactions due to the effect of the tetrafluoro-substituted benzene ring as an acceptor substituent on the vinyl groups of the monomer.
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