Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2017 год, номер 1

ZINC HALIDE COMPLEXES OF THIONICOTINAMIDE; CRYSTAL STRUCTURE OF DICHLORIDO BIS(THIONICOTINAMIDE-kN)ZINC(II)

M. Akhtar1, M.R. Malik1, M.N. Tahir2, S. Nadeem1, M. Altaf3, M. Sohail3, S. Ali1, S. Ahmad4
1Quaid-i-Azam University, Islamabad, Pakistan
2University of Sargodha, Sargodha, Pakistan
3King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
4Prince Sattam bin Abdulaziz University, Al-Kharj, Saudi Arabia
saeed_a786@hotmail.com
Ключевые слова: zinc(II), thionicotinamide, NMR spectroscopy, crystal structure
Страницы: 185-189

Аннотация

Zinc halide complexes of thionicotinamide (TNA) having the general formula [Zn(TNA)2X2] (X = Cl-, Br-, I-) are prepared and characterized by thermal analysis, IR and NMR spectroscopy. The crystal structure of one of them, dichloridobis(thionicotinamide-кN)zinc(II), [Zn(TNA)2Cl2] (1), is determined using X-ray crystallography. In 1, the zinc atom is coordinated by two thionicotinamide ligands through nitrogen atoms and two chloride ions in a distorted tetrahedral coordination environment. The molecular structure of the complex is stabilized through intermolecular hydrogen bonding.

DOI: 10.15372/JSC20170124
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