CRYSTAL STRUCTURE OF A NEW MANGANESE(III) COMPLEX WITH TETRADENTATE SCHIFF BASE N,N'-O-PHENYLENEBIS(4-METHOXYSALICYLIDENEIMINE)
A. Ghaemi1, B. Keyvani1, S. Rayati2, S. Zarei1, B. Notash3
1Islamic Azad University, Saveh, Iran
akbar.ghaemi@yahoo.com
2K.N. Toosi University of Technology, Tehran, Iran
3Shahid Beheshti University, G.C., Evin, Tehran 1983963113, Iran
Ключевые слова: synthesis, tetradentate Schiff base ligand, Mn(III), crystal structure, N,N'-O-phenylenebis(4-methoxysalicylideneimine), X-ray diffraction analysis
Страницы: 1078-1081
Аннотация
A new manganese(III) complex [Mn(L)(NCS)] (1) is synthesized from the Schiff base ligand N,N¢- O -phenylenebis(4-methoxysalicylideneimine) (H2L: derived from the condensation of 4-methoxy salicylaldehyde with O -phenylene-diamine) with Mn(NO3)2×4H2O and KSCN in a methanol/water solvent mixture. This complex is characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. It crystallizes in a monoclinic system, with space group P 21/ c and four molecules in the unit cell ( Z = 4). The crystal structure shows [Mn(L)(NCS)] units joined together by the Mn⋯S secondary bonding interaction (SBI) to form infinite zigzag chain structures.
DOI: 10.15372/JSC20160525 |
