Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2016 год, номер 3

CRYSTAL STRUCTURE OF PALLADIUM(II) COMPLEX WITH 2,2'-DIPYRIDYLAMINE AND 4-TOLUENESULFONYL-L-SERINE

E. Mehdipour1, H. Bahrami1, S. Shamaei2, V. Amani2
1Lorestan University, Khoramabad, Iran
e_mehdipour@yahoo.com
2Islamic Azad University, Tehran, Iran
Ключевые слова: crystal structure, palladium(II) complex, 4-toluenesulfonyl-L-serine, 2,2'-dipyridylamine, thermal gravimetric, differential thermal analyses, luminescent properties
Страницы: 564-571

Аннотация

The [Pd(dpa)(tsser)] complex (1) is prepared from the reaction of PdCl2 and 2,2'-dipyridylamine (dpa) with 4-toluenesulfonyl-L-serine (tsserH2). This complex is characterized by spectral methods (IR, UV-Vis, 1H NMR, and luminescence), elemental analysis, thermal analysis (TG, DTA), and single crystal X-ray diffraction. X-ray structure determinations show that in this complex, PdII atoms are four-coordinated in a distorted square-planar configuration by two N atoms from a bidentate 2,2'-dipyridylamine ligand and one N atom and one O atom from a bidentate tsser2- ligand.

DOI: 10.15372/JSC20160316
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