Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2015 год, номер 8

STUDIES ON SPECTROSCOPIC AND CRYSTAL STRUCTURE OF DICHLORO CARBONYL DIPYRIDINE TRIPHENYLARSINE RUTHENIUM(II) COMPLEX

M. Gowri1, T. Srinivasan2, D. Velmurugan2
1Avinashilingam University for Women, Coimbatore - 641 043, Tamilnadu, India
sriadit.gowrisuresh@gmail.com
2University of Madras, Guindy Campus, Chennai - 600 025, Tamilnadu, India
srini771@gmail.com
Ключевые слова: Ru(II) complex, triphenyl arsine, pyridine, chloride, carbonyl complex, crystal structure
Страницы: 1664-1667

Аннотация

The title complex [Ru(Cl)2(CO)(py)2(AsPh3)], was synthesized and characterized. The molecular structure and crystal structures are determined by X-ray crystallography. The dihedral angle between the two cis -pyridine rings is 73.3(2)°, which shows that they are almost orthogonal to each other. The molecular structure is stabilized by inter-molecular and intra-molecular C-H…Cl interactions. The molecular structure is further stabilized by interactions between the aromatic rings.

DOI: 10.15372/JSC20150822
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