Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2015 год, номер 3

STRUCTURAL CHARACTERIZATION OF TETRAKIS(1,3-DIAZINANE-2-THIONE)CADMIUM(II) SULFATE

R. Mahmood1, S.G. Hussain2, A.A. Isab3, M. Fettouhi3, A. Fazal3, S. Ahmad2
1University of Azad Jammu and Kashmir, Chela Campus, Muzaffarabad, Pakistan
2University of Engineering and Technology, Lahore, Pakistan
saeed_a786@hotmail.com
3King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
Ключевые слова: cadmium sulfate, 1,3-diazinane-2-thione, crystal structure
Страницы: 492-497
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

A cadmium(II) complex tetrakis(1,3-diazinane-2-thione)cadmium(II) sulfate [Cd(Diaz)4]SO4 (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of 1 consists of [Cd(Diaz)4]2+ and SO42- ions. In the complex ion, the central cadmium atom is coordinated by four Diaz molecules through sulfur atoms adopting a distorted tetrahedral geometry. The molecular structure is stabilized by N-H…O and N-H…S hydrogen bonding interactions. The complex is also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

DOI: 10.15372/JSC20150309