Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2014 год, номер 6

CRYSTAL STRUCTURE OF DIGUANIDINIUM DIAQUAPENTAKIS(NITRATO)NEODYMIATE(III)

W.N. William
University of New Mexico, Albuquerque, NM 87131, USA
wwillia1@unm.edu., william.wilson@sekomu.ac.tz., wilsonngambeki@yahoo.com
Ключевые слова: crystal structure, neodymium nitrate complex, guanidinium cation, hydrogen bonding
Страницы: 1178-1181
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

The crystal structure of the C 2H 16N 11NdO 17 complex ( I) is established by X-ray crystallography. Compound ( I) crystallizes in the monoclinic system, space group C2/ c, a = 10.8926(6) Å, b = 9.0003(6) Å, c = 20.4621(11) Å, α = 90°, β = 94.535(3)°, γ = 90°, V = 1999.8(2) Å 3, and Z = 4. The guanidinium N-H and water H atoms are engaged in hydrogen bonds with an oxygen atom of the nitrate groups attached on neodymium (Nd). This has resulted in the formation of a three dimensional network. Based on the Cambridge Structural Database, this is the first structurally-characterized neodymium nitrate anion bonded to the [(NH 2) 3C] + cation.