Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2014 год, номер 1

CRYSTAL STRUCTURE OF A Mn(II) COMPLEX WITH ISATIN-HYDRAZONE-S-BENZYLDITHIOCARBAZATE

J.-J. Xia
Anhui University of Architecture, Hefei, P. R. China
xiajj@aiai.edu.cn
Ключевые слова: X-ray diffraction, dithiocarbazate, isatin, manganese(II) acetate
Страницы: 135-138
Подраздел: КРАТКИЕ СООБЩЕНИЯ

Аннотация

The reaction of Mn(OAc)2·4H2O with isatin-hydrazone-S-benzyldithiocarbazate (HIsa-SBn) results in the formation of a bis-ligand complex [Mn(Isa-SBn)2]·2DMF. Its single crystal is obtained and the structure is determined by X-ray diffraction. It belongs to a monoclinic space group C2/ c with the cell parameters: a = 23.290(4) Å, b = 11.4980(18) Å, c = 18.483(5) Å, V = 4087.6(14) Å3. The Mn(II) atom is six-coordinated with two amide O atoms, two azomethine N atoms, and two thiolate S atoms, resulting in a distorted octahedral geometry.