Издательство СО РАН

Издательство СО РАН

Адрес Издательства СО РАН: Россия, 630090, а/я 187
Новосибирск, Морской пр., 2

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Яндекс.Метрика

Поиск по журналу

Журнал структурной химии

2013 год, номер 3

CADMIUM(II) COMPLEX WITH (1'H-[2,2']BIIMIDAZOLY-1-YL)-ACETIC ACID: SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENCE

J. Wang, J.-Q. Tao, X.-J. Xu, C.-Y. Tan
Department of Chemistry, Yancheng Teachers' College, Yancheng, Jiangsu, P.R. China
wjyctu@gmail.com
Ключевые слова: Cd(II) complex, crystal structure, hydrogen bonding, C—O…π interaction, photoluminescence
Страницы: 502-505
Подраздел: КРИСТАЛЛОХИМИЯ

Аннотация

A new cadmium(II) complex with (1'H-[2,2']Biimidazoly-1-yl)-acetic acid (HBDAC) [Cd(BDAC)2(H2O)2]×H2O is synthesized and structurally characterized, which crystallizes in the monoclinic system, space group P21/c , a = 8.465(3) Å, b = 14.164(5) Å, c = 11.294(3) Å, α = 90°, β = 127.405(17)°, γ = 90°, Z = 2. The [Cd(BDAC)2(H2O)2]·H2O units are further bridged by O—HO, N—HO, C—HO hydrogen bonds, π—π stacking and C—Oπ interactions, generating a three-dimensional supramolecular structure. In addition, luminescence measurements reveal that complex 1 exhibits strong fluorescent emission in the solid state at room temperature.