MULTIPLE SULFUR ISOTOPE COMPOSITIONS IN MESOARCHEAN SULFIDE DEPOSITS OF THE KARELIAN CRATON: IMPLICATIONS FOR DETERMINING THE SULFUR SOURCE, BIOGEOCHEMICAL PROCESSES, AND DEPOSIT GENESIS
S.V. Vysotskiy1, T.A. Velivetskaya1, A.V. Ignatiev1, L.V. Kuleshevich2, A.I. Slabunov2
1Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences, pr. 100-letiya Vladivostoka 159, Vladivostok, 690022, Russia
2Institute of Geology, Karelian Research Center of the Russian Academy of Sciences, ul. Pushkinskaya 11, Petrozavodsk, 185910, Russia
Keywords: Sulfur isotopes, mass-independent fractionation, massive sulfide deposits, Archean, Karelian Craton
Abstract
In the present paper we demonstrate that most sulfides of the studied deposits of the Archean Sumozero-Kenozero greenstone belt within the Karelian Craton on the Fennoscandian Shield have nonzero Δ33S values. This indicates that proportions of seawater sulfate and elemental sulfur in Mecoarchean included into the ores and resulting from UV photolysis, are different. Our results show that systematics of sulfur isotopes of sulfides generally reflects the mixing of mass-independently fractionated sulfur reservoirs with positive and negative Δ33S values. Pyrite is depleted in 34S isotope, which was interpreted as evidence for microbial sulfate reduction. Variations in the positive Δ33S anomalies of the Leksa deposit and the general tendency for Δ33S sulfide content to increase with stratigraphic levels in certain boreholes most likely reflect the change in temperature and the fluid mixing throughout the life of the hydrothermal system. The presence of sulfides with strongly negative Δ33S anomalies suggests that atmospheric sulfur and seawater sulfate, rather than volcanic sulfur, were the prevailing source for mineral systems of the studied deposits. The presented data require the Mesoarchean seawater to contain sulfates at least locally.
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