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Combustion, Explosion and Shock Waves

2019 year, number 6

Direct Conversion of Chemical Energy into Electric Energy in the Combustion of a Thin Three-Layer Charge

V. Yu. Barinov1, D. Yu. Kovalev1, S. G. Vadchenko1, O. A. Golosova1, V. V. Prosyanyuk2, I. S. Suvorov2, S. V. Gil'bert2
1Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, 142432 Russia
2Research Institute of Applied Chemistry, Sergiev Posad, 141313 Russia
Keywords: горение, ЭДС горения, энергетические конденсированные системы, высокотемпературный гальванический элемент, combustion, EMF of combustion, energy condensing systems, high-temperature galvanic cell

Abstract

This paper presents a study of direct conversion of chemical energy into electrical energy during the combustion of a (80Zr + 20CuO) - (LiF + CaF2 + MgF2) - (15Zr + 85CuO) thin three-layer condensed energy system, which is a high-temperature galvanic cell. It is determined that this cell during combustion generates an electric signal with an amplitude of 1.6 V and a half-width of 15 s. Its formation mechanism is proposed. A time-resolving X-ray diffraction method is used to identify the phases formed.