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Russian Geology and Geophysics

2019 year, number 6

LATERAL ZONING OF GROUNDWATER CHEMISTRY AND AUTHIGENIC MINERALOGY IN THE OXFOR-DIAN REGIONAL RESERVOIR OF THE NADYM–TAZ INTERFLUVE

D.A. Novikov1,2, L.G. Vakulenko1,2, and P.A. Yan1

1A.A. Trofimuk Institute of Petroleum Geology and Geophysics, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia

2 Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia


Keywords: Lateral zoning, authigenic minerals, groundwater chemistry, water-rock system, water-mineral complex, catagenesis, Upper Jurassic, West Siberia, Arctic

Abstract

This is a pioneering study on lateral zoning of groundwater chemistry and authigenic mineralogy in the Oxfordian regional reservoir of the Nadym–Taz interfluve. According to thermodynamic calculations, the nonequilibrium–equilibrium water–rock system lacks equilibrium with primary magmatic minerals, such as al-bite, anorthite, and microcline, though the water is moderately saline (up to 63.3 g/L) and has been in interaction with rocks for ~165 million years. Authigenic minerals form continuously and successively (kaolin-ite–montmorillonite–illite–micas–chlorite–albite–microcline) fr om waters that have certain ðH and contents of SiO2, Al, Na, K, Ca, and Mg. The equilibrium of groundwater with primary aluminosilicate minerals impinges on a carbonate barrier, and almost all rocks are more or less strongly carbonatized. Authigenic mineral assem-blages from the southern Nadym–Taz interfluve include kaolinite unlike those from the northern part of the re-gion wh ere albitization is more common. Authigenesis generally decays in the eastern direction.

DOI: 10.15372/RGG2019041