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Combustion, Explosion and Shock Waves

2019 year, number 2

Thermochemical and Energy Characteristics of DAzFF and AzNTF

D. B. Lempert1, A. I. Kazakov1, V. S. Sannikov2, A. V. Nabatova1, D. V. Dashko2, A. I. Stepanov2
1Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432 Russia
2Tekhnolog Special Design and Technological Bureau, St. Petersburg, 193076 Russia
Keywords: 3,4-бис(4-азидофуразан-3-ил)фуроксан, 4-азидо-4''-нитро-3,3':4','3'-терфуразан, теплота сгорания, энтальпия образования, смесевое твердое ракетное топливо, удельный импульс, 3,4-bis (4-azidofurazan-3-yl) furoxan, 4-azido-4'-nitro-3,3':4','3'-terfurazan, heat of combustion, enthalpy of formation, composite solid propellant, specific impulse

Abstract

The heat of combustion and standard the formation enthalpy of 3,4-bis (4-azidofurazan-3-yl) furoxan (DAzFF) and 4-azido-4'$-nitro-3,3':4','3'-terfurazan (AzNTF) were experimentally determined. Thermodynamic analysis was performed to investigate the efficiency of these compounds as potential components of metal-free composite solid propellants based on an active binder with the possibility of introducing an additional small additive oxidant with a high oxygen content, such as ammonium perchlorate.