Home – Home – Jornals – Russian Geology and Geophysics 2018 number 12

The paper is focused on the evolution of the Earth starting with the planetary accretion and differentiation of the primordial material (similar in composition to CI chondrites) into the core and mantle and the formation of the Moon as a result of the impact of the Earth with a smaller cosmic body. The features of the Hadean eon (ca. 4500-4000 Ma) are described in detail. Frequent meteorite-asteroid bombardments which the Earth experienced in the Hadean could have caused the generation of mafic/ultramafic primary magmas. These magmas also differentiated to produce some granitic magmas, from which zircons crystallized. The repeated meteorite bombardments destroyed the protocrust, which submerged into the mantle to remelt, leaving refractory zircons, indicators of the Early Earth’s geologic conditions, behind. The mantle convection that started in the Archean could possibly be responsible for the Earth’s subsequent endogenous evolution. Long-living deep-seated mantle plumes could have promoted the generation of basalt-komatiitic crust, which, thickening, could have submerged into the mantle as a result of sagduction, where it remelted. Partial melting of the thick crust, leaving eclogite as a residue, could have yielded tonalite-trondhjemite-granodiorite (TTG) melts. TTG rocks are believed to compose the Earth’s protocrust. Banded iron bodies, the only mineral deposits of that time, were produced in the oceans that covered the Earth. This environment, recognized as LID tectonics combined with plume tectonics, probably existed on the Earth prior to the transitional period, which was marked by a series of new geologic processes and led to a modern-style tectonics, involving plate tectonics and plume tectonics mechanisms, by 2 Ga. The transitional period was likely to be initiated at about 3.4 Ga, with the segregation of outer and inner cores, which terminated by 3.1 Ga. Other rocks series (calc-alkaline volcanic and intrusive) rather than TTGs were produced at that time. Beginning from 3.4-3.3 Ga, mineral deposits became more diverse; noble and siderophile metal occurrences were predominant among ore deposits. Carbonatites, hosting rare-metal mineralization, could have formed only by 2.0 Ga. From 3.1 to 2.7 Ga, there was a period of “small-plate” tectonics and first subduction and spreading processes, which resulted in the first supercontinent by 2.7 Ga. Its amalgamation indicates coupling of superplume-supercontinent cycles. Between 2.7 and 2.0 Ga, a D” layer formed at the core-mantle interface. It became a kind of thermal regulator to keep the constant temperature of the ascending already tholeiitic mantle plume magmas. All deep-seated layers of the Earth and large low-velocity shear provinces, called mantle hot fields, partially melted enriched EM-I and EM-II mantles, and the depleted recent astenosphere mantle, which is parental for midocean-ridge basalts, were finally generated by 2 Ga. Therefore, an interaction of all Earth’s layers began from that time.

Geological, geochronological, and isotope-geochemical studies of the metadolerites of the Angaul complex, widespread in the Urik-Iya graben of the southern Siberian craton, were carried out. The metadolerites forming separate conformal bodies (sills) among the metasandstones of the Ingash Formation were studied in detail. U-Pb zircon (SHRIMP) dating of metadolerites yielded an age of 1913 ± 24 Ma, and U-Pb baddeleyite (ID-TIMS) dating of these rocks yielded an age of 1914.0 ± 1.7 Ma. Thus, the date of 1914 ± 2 Ma can be taken as the most precise age estimate for the studied rocks. The metadolerites of the Angaul complex correspond in chemical composition to the normal-alkaline tholeiitic basalts. Metadolerites are differentiated rocks with Mg# of 36 to 58. They show fractionated REE patterns: (La/Yb) n = 1.2-3.5. All metadolerites, independently of their Mg# value, have low contents of Nb (1.6-10.2 ppm) and show well-pronounced negative Nb-Ta anomalies in multielement patterns (Nb/Nb* = 0.19-0.54). The metadolerites are characterized by positive εNd(T) values ranging from 0.4 to 5.2, which correlate well with their SiO2 content and Mg# value. The isotope-geochemical parameters of the metadolerites of the Angaul complex indicate that fractional crystallization, along with the assimilation of the host rocks (AFC), might have been the main process during the formation of the most differentiated metadolerites. The geochemical characteristics of metadolerites with the maximum Mg# values of 57-58 and εNd(T) = 5.2 suggest that the parental mantle source of the metadolerites resulted from mixing of predominant depleted mantle material with the subcontinental-lithosphere material. Intrusion of the dolerites of the Angaul complex, as well as the deposition of the sedimentary strata of the Ingash Group, took place at the Early Proterozoic stage of intracontinental extension caused by the collapse of the orogen resulted from the collision of the Biryusa block with the Tunguska superterrane in the southern Siberian craton.

This paper reports isotopic and geochemical studies of eclogites from the western ultrahigh pressure (UHP) and eastern high-pressure (HP) blocks of the Kokhetav subduction-collision zone. These HP and UHP eclogites exhumed in two stages: (1) The rocks of the western block metamorphosed within the field of diamond stability (e.g., Kumdy-Kol and Barchi); (2) In contrast, the metamorphic evolution of the eastern block reached the pressure peak within the of coesite stability (e.g., Kulet, Chaglinka, Sulu-Tyube, Daulet, and Borovoe). The eclogites vary widely in the ratios of incompatible elements and in the isotope ratios of Nd (¹⁴³Nd/¹⁴⁴Nd = = 0.51137-0.513180) and Sr (87Sr/86Sr = 0.70393-0.78447). The Sulu-Tyube eclogites display isotope-geochemical features close to N-MORB, while those from the other sites are compositionally similar to E-type MORB or island arc basalts (IAB). The model ages T_Nd(DM) of eclogites vary between 1.95 and 0.67 Ga. The Sulu-Tyube eclogite yields the youngest age; it has the values of ε_Nd( T ) (7.2) and ⁸⁷Sr/⁸⁶Sr (0.70393) close to the depleted-mantle values. The crustal input to the protolith of the Kokchetav eclogites is evident on the ε_Nd(T)-⁸⁶Sr/⁸⁷Sr and ε_Nd( T )-T plots. The eclogites make up a trend from DM to country rocks. Some eclogites from the Kulet, Kumdy-Kol, and Barchi localities display signs of partial melting, such as high Sm/Nd (0.65-0.51) and low (La/Sm)_N (0.34-0.58) values. The equilibrium temperatures of these eclogites are higher than 850 ºC. The geochemical features of eclogites testify to the possibility of the eclogite protolith formation in the tectonic setting of passive continental rift margin subducted to depths over 120 km.

Based on the geochemical characteristics of the Miocene-Quaternary volcanic rocks of the Sredinny Range of Kamchatka, we divide it into northern and southern provinces; the latter comprises the «eastern», «western», and «central» flanks. We present new data on the composition of Neogene-Quaternary volcanic rocks in the southern part of the Sredinny Range of Kamchatka: Khangar and Icha volcanic massifs and Mt. Yurtinaya on the «western» flank, Bystrinsky and Kozyrevsky Ridges on the «eastern» flank, and Anaunsky Dol and Uksichan massif located in between. We show systematic differences in the composition of rocks from the «western» and «eastern» flanks. During the Neogene, a typical island-arc volcanism took place within the «eastern» flank. Quaternary volcanic rocks of this area have both island-arc and within-plate geochemical features. We propose to call rocks of this type hybrid rocks. Within the «western» flank, hybrid volcanism has been manifested since the Neogene, while typical island-arc rocks are not found. Magma generation processes on the «western» flank of the Sredinny Ridge are influenced by the enriched mantle source; the effect of fluid is less pronounced here as compared to the rocks of the «eastern» flank, where it is clearly traced.

Contents of platinum group elements (PGE - Os, Ir, Ru, Rh, Pt, and Pd) and rhenium in basalts of different geochemical types from the ophiolite complex of the Kamchatsky Mys Peninsula have been determined by the isotope dilution-mass spectrometry method. The total contents of PGE in different basalts are commensurate (1.4-3.6 ppb), but the element ratios vary considerably. A specific feature of the rocks is the low degree of PGE fractionation (Pd/Ir = 0.9-6.6, Pt/Pd = 1.0-7.3), which makes them similar to the Hawaiian tholeiitic basalts and picrites. The most fractionated PGE pattern is observed for alkali basalt (Pd/Ir = 6.6), and the least fractionated one, for E-MORB (Pd/Ir = 1.7). The similarity of the PGE patterns of basalts of different geochemical types suggests their similar mantle sources. We propose a model explaining the geochemical features of the basalts of the Kamchatsky Mys ophiolite complex by an impurity of the Earth’s core material in the plume source. The Ir/Pd-Ru/Pd and Pd/10-Ir-Ru discrimination diagrams can be used to identify enriched (plume) basalts based on their PGE content.

We study the behavior of a number of siderophile elements, including platinum-group elements, during the formation of the Medek dunite-wehrlite massif. Its structural position, internal structure, and mineralogical composition are presented; a 3D geochemical model is constructed. The forsterite content of olivine varies from 90 to 73% from top to bottom of the vertical cross section of the massif. In addition, there are a decrease in the volume content of olivine and the appearance of ilmenite instead of accessory Cr-spinel. The observed zonation in variations in the composition of rocks and minerals is consistent with magmatic differentiation in a sheet-like body, which changed its primary occurrence. A geodynamic scenario is proposed, which links the formation of the massif with the break-up of Rodinia and the further changes in the primary occurrence with subsequent accretion-collision events on the southern and southwestern margins of the Siberian craton in the period 600-450 Ma.

Overall petrologic and geochemical data indicate that the early Paleozoic magmatism in the Olkhon area of the Baikal Region exhibits diverse types of granitoids, whose time of formation is estimated at a narrow age interval of 500-465 Ma. This magmatism was responsible for the formation of both autochthonous gneiss-migmatite-granitoid suites (Sharanur complex) and multiphase intrusions (Aya complex) emplaced into the upper horizons of the continental crust. In major-element chemistry, K₂O/Na₂O values, and rare-element composition the migmatite-plagiogranites and calc-alkaline and subalkaline granitoids of the Sharanur complex are similar to the host gneisses and schists, as they were likely derived from melting of the ancient metamorphic substratum of the Olkhon series. In new isotope-geochemical characteristics (ICP MS method) the Sharanur granitoids are close to the first-phase biotite granites of the Aya massif, whose further geochemical evolution was governed mainly by intrachamber magmatic differentiation leading to the production of second-phase leucogranites enriched in HREE and HFSE (in particular, Ta and Nb) and depleted in Sr, Ba, Eu, Li, and LREE. The origin of the autochthonous and intrusive granitoids is related to Early Paleozoic collision events within the Olkhon metamorphic terrane, while the formation of syncollisional granitoids is best explained by both melting of the crust protolith (Sharanur complex) and magmatic differentiation (multiphase Aya intrusion). All mineralogical and geochemical characteristics indicate that these granitoids are distinguished from rare-metal pegmatoid granites and Li-F and Rb-Be-Nb pegmatites, whose vein bodies crosscut the granitoids, and are regarded as Middle Paleozoic rocks, which mark the transition to within-plate magmatism in the Baikal Region.

On the background of Early Paleozoic precollisional, syncollisional, and late collisional igneous rocks prevailing in the region (Khaidai and Shara-Nur granitoids and Birkhin gabbroid complex), rare-metal pegmatoid granite bodies and pegmatites along the southern edge of the Ol’khon region are of particular interest. They have a Middle Paleozoic age (390-391 Ma), cut the Caledonides, and belong to different geochemical types. The Anga unit includes amazonite-containing Li-F-B pegmatites, which are also enriched in Ta, Nb, and W. In the Ol’khon Group, only one K-feldspathic body rich in Rb, Be, Nb, W, Sn, Sc, U, and Th, with large crystals of aquamarine, has been found. The compositions of granite-pegmatite bodies and accessory rare-metal minerals have been studied. The rare-metal granite-pegmatites probably form a peripheral zone of the Hercynian within-plate setting widespread in the eastern Baikal area and related to the influence of the Siberian hot spot.

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (<1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.

We present new data on the age, composition, and environments of formation of granites of the Kystarys complex and the associated Li-rich rare-element pegmatites of the South Sangilen pegmatite belt including the large Tastyg lithium deposit. It has been established that they formed during the Early Paleozoic collisional orogeny in the Tuva-Mongolian massif at the Cambrian-Ordovician boundary. The granites of the Kystarys complex are moderately alkaline high-K rocks and are enriched in Zr, Nb, Y, and REE; therefore, they are classified as postcollisional, transitional to within-plate ( A -type). The spodumene pegmatites of the South Sangilen pegmatite belt are similar to the above granites in age and isotopic and geochemical parameters, which suggests a paragenetic relationship between these rocks. Pegmatites form several pegmatite fields within the belt, which differ in trace-element signatures. In addition to predominant Li, Cs, and Ta, specific to all spodumene pegmatites (LCT family), pegmatites of two fields have high contents of Nb, Y, REE, and Zr, which are indicator elements of NYF family pegmatites. It has been established that the formation of spodumene pegmatites with combined LCT-NYF geochemical signatures was preceded by the intrusion of dikes of monzogabbro with the geochemical characteristics of OIB and of alkali aegirine granites and by the formation of associated metasomatites enriched in Zr, Nb, Y, and REE. Based on the geological, mineralogical, and geochemical data, we substantiate the hypothesis of the formation of Li-bearing granite-pegmatite melts from a mixed source resulted from the influence of fluids of an alkaline igneous complex of mantle genesis on the crustal protolith.

As shown by geological, mineralogical, and isotope geochemical data, trachybasaltic-trachytic-trachyrhyolitic (TTT) rocks from the Nyalga basin in Central Mongolia result from several eruptions of fractionated magmas within a short time span about 120 Ma. Their parental basaltic melts formed by partial melting of mantle peridotite which was metasomatized and hydrated during previous subduction events. Basaltic trachyandesites have high TiO₂ and K₂O, relatively high P₂O₅, and low MgO contents, medium ⁸⁷Sr/⁸⁶Sr₍₀₎ ratios (0.70526-0.70567), and almost zero or slightly negative ε_Nd( T ) values. The isotope geochemical signatures of TTT rocks are typical of Late Mesozoic basaltic rocks from rift zones of Mongolia and Transbaikalia. The sources of basaltic magma at volcanic centers of Northern and Central Asia apparently moved from a shallower and more hydrous region to deeper and less hydrated lithospheric mantle (from spinel to garnet-bearing peridotite) between the Late Paleozoic and the latest Mesozoic. The geochemistry and mineralogy of TTT rocks fit the best models implying fractional crystallization of basaltic trachyandesitic, trachytic, and trachyrhyodacitic magmas. Mass balance calculations indicate that trachytic and trachydacitic magmas formed after crystallization of labradorite-andesine, Ti-augite, Sr-apatite, Ti-magnetite, and ilmenite from basaltic trachyandesitic melts. The melts evolved from trachytic to trachyrhyodacitic and trachyrhyolitic compositions as a result of prevalent crystallization of K-Na feldspar, with zircon, chevkinite-Ce, and LREE-enriched apatite involved in fractionation. Trachytic, trachyrhyodacitic, and trachyrhyolitic residual melts were produced by the evolution of compositionally different parental melts (basaltic trachyandesitic, trachytic, and trachyrhyodacitic, respectively), which moved to shallower continental crust and accumulated in isolated chambers. Judging by their isotopic signatures, the melts assimilated some crustal material, according to the assimilation and fractional crystallization (AFC) model.

Published data on extremely magnesian olivine (>96 mol.% forsterite) in igneous rocks were generalized and compared with data of new high-precision electron probe microanalyses of olivine from oxidized lavas of the Volcano Tolbachik (Kamchatka), chromitites from the Ray-Iz deposit (Russia), alkaline ultrabasic lavas from San Venanzo volcanoes (Italy), and skarns from the Kuh-i-Lal deposit (Tajikistan). All the found olivines resulted from low-temperature processes, such as subsurface oxidation, interaction with carbonates, and subsolidus re-equilibration. Low-temperature formation of olivine is reflected in its structure (hematite lamellae and abundance of inclusions of ore minerals) and abnormal contents of minor components (Mn, Ni, and Ca). The Mg content of olivine increases under the influence of postmagmatic processes and can be manifested in different rocks. This gives grounds to refine the genesis of olivine of exotic composition (93-96 mol.% forsterite) in some kimberlites, komatiites, and peridotites.

The interfacial crystal layer of poorly soluble mineral grown under hydrothermal conditions is modified chemically into a surficial nonautonomous phase (SNAP) and, in this capacity, takes part in growth process, doing several important functions. This paper considers some of them related to geochemistry and mineralogy. The new interpretation is given to the following phenomena: (1) selection of components during crystal growth in multiphase associations; (2) stability of multiphase parageneses having a common chemical component; (3) dual character of the distribution coefficients due to different properties of the crystal volume and SNAP; (4) formation of nano- and microinclusions of unusual composition different from the basic mineral phase; (5) spatial ordering of nano- and microparticles during their directed aggregation at the growing crystal face; (6) accumulation of valuable components (primarily noble metals), incompatible in most of mineral matrixes, in the surficial layer; and (7) effect of “hidden” metal content, associated with the presence of noble metals in the SNAP or of nano- and microinclusions formed during the SNAP evolution.