STRUCTURE OF A NEW CHELATE COMPLEX Mo2O3(dpm)4
A. Yu. Ledneva1, S. B. Artemkina1, P. A. Stabnikov1, L. V. Yanshole2, V. E. Fedorov1
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords: синтез, молибден, кристаллическая структура, термический анализ, масс-спектр, synthesis, molybdenum, crystal structure, thermal analysis, mass spectrum
Abstract
A new Mo2O3(dpm)4 compound (I) is synthesized by the interaction of Mo(CO)6 with 2,2,6,6-tetramethylheptanedione-3,5 (dpm). The structure of complex I determined by the XRD method is as follows: triclinic crystal system, space group P-1, a = 10.1780(7) Å, b = 10.1817(6) Å, c = 13.3255(9) Å, α = 110.562(2)°, β = 102.233(2)°, γ = 93.9041(19)°, V = 1248.17(14) Å3. The compound is characterized by IR spectroscopy, mass-spectrometry and thermogravimetric analysis (TGA).
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