CRYSTAL STRUCTURE, AND PHYSICAL PROPERTIES OF A ONE-DIMENSIONAL COORDINATION POLYMER BASED ON 2,2'-BIS(1H-1,2,4-TRIAZOLYL)ETHER
X.X. Juan, Z. Zhou, L. Li, J.-Q. Tao
Yancheng Teachers University, Yancheng, Jiangsu, P.R. China
Keywords: Cu(II) complex, 2,2'-bis(1H-1,2,4-triazolyl)ether, one-dimensional chain, magnetic property, photocatalytic degradation activity
Abstract
A one-dimensional Cu(II) complex [Cu(BTE)2(ClO4)2] n (1) (BTE = 2,2'-bis(1H-1,2,4-triazolyl)ether) is synthesized and characterized using single crystal X-ray diffraction, IR, and elemental analysis. Single crystal X-ray diffraction analysis reveals that complex 1 is a one-dimensional chain based on the rhomboid subunit [Cu2(BTE)2] with a Cu…Cu separation of 9.0912(2) Å. There is no magnetic coupling between the CuII ions. Complex 1 displays a high photocatalytic degradation activity for methylene blue.
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