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Journal of Structural Chemistry

2017 year, number 1

STRUCTURE OF A BIMOLECULAR CRYSTAL OF 2,4,6,8,10,12-HEXANITRO-2,4,6,8,10,12-HEXAAZAISOWURTZITANE AND METHOXY-NNO-AZOXYMETHANE

I. N. Zyuzin, Z. G. Aliev, T. K. Goncharov, E. L. Ignatieva, S. M. Aldoshin
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia
Keywords: алкокси-NNO-азоксисоединения, метокси-NNO-азоксиметан, Z-2-метокси-1-метилдиазен 1-оксид, CL-20, бимолекулярные кристаллы, кристаллическая структура, alkoxy-NNO-azoxy compounds, methoxy-NNO-azoxymethane, Z-2-methoxy-1-methyldiazene 1-oxide, CL-20, bimolecular crystals, crystal structure

Abstract

The crystal structure of the bimolecular crystal of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and methoxy- NNO -azoxymethane (МАМ) (1:2) is studied. The CL-20 molecules adopt a z-conformation. The crystal structure is formed by layers of CL-20 and МАМ molecules, between which there are shortened NOd-⋯Nd+O contacts of the neighboring CL-20 and МАМ molecules.