CRYSTAL STRUCTURES OF [RhL4Cl2][AuCl4] (L = Py, Оі- AND ОІ-PICOLINES) COMPLEX SALTS
D. B. Vasilchenko1,2, E. Yu. Semitut1,3, E. A. Bykova4, S. V. Korenev1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
3National Research Tomsk Polytechnic University, Tomsk, Russia
4University of Bayreuth, Bayreuth, Germany
Keywords: синтез, родий, пиридин, пиколин, золото, рентгеноструктурный анализ, synthesis, rhodium, pyridine, picoline, gold, single crystal X-ray diffraction analysis
Abstract
New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]- complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.
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