APPLICATIONS OF NUCLEAR MAGNETIC RESONANCE TO STUDY THE STRUCTURE OF PLATINUM-GROUP METAL COMPLEXES IN AQUEOUS SOLUTIONS
M. A. Fedotov†
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
Keywords:
, Ru
, Rh
, Pd
, Os
, Pt ЯМР
, комплексы платиновых металлов, водные растворы, координатный сдвиг, неорганические лиганды, аминокислотные лиганды, радиоактивные отходы, Pt NMR
, platinum metal complexes, aqueous solutions, coordinate shift, inorganic ligands, amino acid ligands, radioactive waste
Abstract
The review includes comprehensive NMR data on platinum metals (99,101Ru, 103Rh, 105Pd, 187Os, 195Pt) and ligand donor atoms (1H, 13C, 14,15N, 17O, 19F, 31P) of metal complexes in aqueous solutions. A systematic analysis of NMR spectroscopy techniques is presented with focus on the measurements of NMR parameters in these systems. A novel concept referred to as coordinate shift is introduced, allowing interpretation of NMR spectra of platinum metal complexes. The review contains an encyclopedic NMR database covering a period of over 50 years from the first measured NMR spectra of platinum metals to 2014.
|
