Structure of an n-Heptane/Toluene Flame: Molecular Beam Mass Spectrometry and Computer Simulation Investigations
D. A. Knyazkov1,2, N. A. Slavinskaya3, A. M. Dmitriev1,2, A. G. Shmakov1,2, O. P. Korobeinichev1, U. Riedel3
1Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2Novosibirsk State University, Novosibirsk, 630090 Russia
3Institute of Combustion Technology, Stuttgart, 70569 Germany
Keywords: образование предшественников сажи, детальный механизм реакций, н-гептан, толуол, молекулярно-пучковая масс-спектрометрия, soot precursor formation, detailed reaction mechanism, n-heptane, toluene, molecular beam mass spectrometry
Abstract
Molecular beam mass spectrometry was used to measure mole fraction profiles of the reactants, major reaction products and intermediates, including precursors of polycyclic aromatic hydrocarbons, in a premixed fuel-rich (equivalence ratio of 1.75) n -heptane/toluene/O2/Ar flame stabilized on a flat burner at atmospheric pressure. The ratio of the liquid volumes in the n -heptane/toluene mixture was7:3. The chemical structure of the flame was modeled using a detailed mechanism of chemical reactions tested against experimental data of other authors on n -heptane/toluene flames and comprising the reactions of formation of polycyclic aromatic hydrocarbons. The mechanism was extended with cross-reactions involving derivatives of n -heptane and toluene. Overall, the new experimental data are in satisfactory agreement with the numerical simulation results; however, there are differences between the measured and calculated mole fraction profiles of some species. Analysis shows that in the n -heptane/toluene flame, the main reactions leading to the formation of low-aromatic compounds (benzene and phenyl) are reactions typical of the pure toluene flame.
|
