STRUCTURE OF THE Os2S2Br4(4-CNPy)4 COMPLEX
S. A. Baranets1, Yu. V. Mironov2,3, A. I. Smolentsev2,3, S. V. Volkov1, L. B. Kharkova1, O. G. Yanko1
1Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: осмий, биядерный кластерный комплекс, кристаллическая структура, osmium, binuclear cluster complex, crystal structure
Abstract
The interaction of the quaternary thioselenobromide complex Os2S7Se5Br8 prepared by the reaction of OsO4 with a solution of sulfur in Sе2Br2 at 100°C with melted 4-CNPy at 165°C leads to the formation of the Os2S2Br4(4-CNPy)4 complex whose structure is determined by single crystal X-ray diffraction.
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