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Journal of Structural Chemistry

2015 year, number 5


A. Yu. Ledneva1, A. V. Virovets1,2, N. G. Naumov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: синтез, рений, октаэдрический кластер, кадмий, синтез, топологическая кристаллохимия, водородная связь, synthesis, rhenium, octahedral cluster, cadmium, synthesis, topological crystal chemistry, hydrogen bond


By single crystal X-ray diffraction, the structure of a new compound based on octahedral mixed-ligand anionic cluster complexes of rhenium and cadmium(II) cations is determined: K 0.4Cs 0.6{Cd(H 2O) 2Re 6S 8(CN) 4(OH)(H 2O)}·8H 2O (1). The compound has a framework structure with a pts (platinum sulfide) topology. The cluster anions are additionally chained together by strong OH…H 2O hydrogen bonds between the terminal ligands of neighboring clusters; the O…O distance is 2.464 Å.