STRUCTURE AND THERMAL PROPERTIES OF THE MOLYBDENUM COMPLEX Mo(acac)3
A. Yu. Ledneva1, S. B. Artemkina1,2, D. A. Piryazev1, V. E. Fedorov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: молибден, ацетилацетон, синтез, кристаллическая структура, термический анализ, molybdenum, acetylacetone, synthesis, crystal structure, thermal analysis
Abstract
A method for the synthesis of the Mo(acac)
3 complex is proposed and its crystal structure is determined by single crystal X-ray diffraction. Space group P 2
1/ c , a = 19.7538(5) Å, b = 7.4821(2) Å, c = 34.6190(8) Å, b = 96.8055(12)°, V = 5080.6(2) Å
3, Z = 12. The compound is studied by the thermogravimetric analysis, and MoO
3 is shown to be the result of its decomposition.
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