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Journal of Structural Chemistry

2015 year, number 5

STRUCTURE OF THE PRODUCT OF 1,8-DIAZABICYCLO[5.4.0]UNDECANE-7-ENE SUBSTITUTION FOR CHLORINE ATOMS IN DICHLORINE SUBSTITUTED Fe(II) CLATHROCHELATE

M. A. Vershinin1, A. B. Burdukov1, N. V. Pervukhina1, I. V. Eltsov2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: клатрохелаты, нуклеофильное замещение, РСА, ЯМР, clathrochelates, nucleophilic substitution, single crystal X-ray diffraction, NMR spectroscopy

Abstract

Methods of X-ray diffraction analysis and nuclear magnetic resonance are used to determine the molecular structure of macrobicyclic boron-capped tris -dioxymate iron(II) clathrochelate containing an annellated 5-membered heterocycle.