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Journal of Structural Chemistry

2015 year, number 5

STAR-LIKE DEXTRAN-POLYACRYLAMIDE POLYMERS: PROSPECTS OF USE IN NANOTECHNOLOGIES

N. V. Kutsevol1, V. A. Chumachenko1, M. Rawiso2, V. F. Shkodich3, O. V. Stoyanov3
1Taras Shevchenko National University of Kyiv, Kyiv, Ukraine
2Institut Charles Sadron, Strasbourg Cedex 2, France 3
3Kazan National Research Technological University, Kazan, Russia
Keywords: декстран, полиакриламид, разветвленный полимер, полиэлектролит, наночастица, dextran, polyacrylamide, branched polymer, polyelectrolyte, nanoparticle

Abstract

Branched star-like dextran-polyacrylamide copolymers in nonionic and ionic forms are used as matrices for the fabrication of silver nanoparticles. It is demonstrated that due to the features of their molecular structure providing a high local concentration of functional groups, branched polymers stabilize silver nanoparticles more efficiently as compared with their linear analogs. Stable silver colloids are obtained in a branched anionic matrix, meanwhile a linear matrix does not stabilize a nanosystem.