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Journal of Structural Chemistry

2015 year, number 5

X-RAY STRUCTURE OF AN AMIDE-APPENDED CHLOROMERCURATED DERIVATIVE OF 2-PHENYLQUINOLINE

C.-Y. Lin, W. Henderson, B.K. Nicholson
University of Waikato, Hamilton, New Zealand
Keywords: synthesis, mercury complexes, orthometallation reactions, crystal structure

Abstract

Reaction of the morpholine amide derivative of 2-phenyl-4-quinolinecarboxylic acid with mercury(II) acetate and lithium chloride results in chloromercuration at the ortho position on the phenyl ring; the complex was characterised by ESI mass spectrometry and an X-ray structure determination.