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Journal of Structural Chemistry

2015 year, number 4

NEW TRINUCLEAR Ој3в€’VINYLIDENE CLUSTER CpReFePt(Ој3в€’C=CHPh)(CO)5[P(OPri)3]2

V. V. Verpekin1, O. S. Chudin1, D. A. Piryazev2,3, A. I. Rubaylo1,4,5, S. A. Gromilov2,3, O. V. Semeikin6
1Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia
2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk National Research State University, Novosibirsk, Russia
4Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia
5Siberian Federal University, Krasnoyarsk, Russia
6Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Keywords: рений, железо, платина, винилиденовые комплексы, гетерометаллические комплексы, кластеры, рентгеноструктурный анали, rhenium, iron, platinum, vinylidene complexes, heterometallic complexes, clusters, single crystal X-ray diffraction study

Abstract

The X-ray diffraction study of a new heterometallic cluster CpReFePt(μ3-C=CHPh)(CO)5[P(OPri)3]2 is performed. The crystallographic characteristics are as follows: a = 11.0275(4) Å, b = 33.0367(12) Å, c = 12.2691(5) Å, β = 98.3660(10)°, V = 4422.2(3) Å3, space group P21/n , Z = 4, dcalc = 1.744 g/cm3. The cluster contains the phenylvinylidene ligand coordinated with a trimetallic core in the form of a Re-Fe-Pt chain (the Re-Fe and Fe-Pt bond lengths are 2.794(7) Å and 2.628(1) Å respectively; the Re∙∙∙Pt distance is 3.354(1) Å).