NEW TRINUCLEAR Ој3в€’VINYLIDENE CLUSTER CpReFePt(Ој3в€’C=CHPh)(CO)5[P(OPri)3]2
V. V. Verpekin1, O. S. Chudin1, D. A. Piryazev2,3, A. I. Rubaylo1,4,5, S. A. Gromilov2,3, O. V. Semeikin6
1Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia 2Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia 3Novosibirsk National Research State University, Novosibirsk, Russia 4Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia 5Siberian Federal University, Krasnoyarsk, Russia 6Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Keywords: рений, железо, платина, винилиденовые комплексы, гетерометаллические комплексы, кластеры, рентгеноструктурный анали, rhenium, iron, platinum, vinylidene complexes, heterometallic complexes, clusters, single crystal X-ray diffraction study
Abstract
The X-ray diffraction study of a new heterometallic cluster CpReFePt(μ3-C=CHPh)(CO)5[P(OPri)3]2 is performed. The crystallographic characteristics are as follows: a = 11.0275(4) Å, b = 33.0367(12) Å, c = 12.2691(5) Å, β = 98.3660(10)°, V = 4422.2(3) Å3, space group P21/n , Z = 4, dcalc = 1.744 g/cm3. The cluster contains the phenylvinylidene ligand coordinated with a trimetallic core in the form of a Re-Fe-Pt chain (the Re-Fe and Fe-Pt bond lengths are 2.794(7) Å and 2.628(1) Å respectively; the Re∙∙∙Pt distance is 3.354(1) Å).
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