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Journal of Structural Chemistry

2014 year, number 6

AN X–RAY SPECTRSCOPY STUDY OF THE ELECTRONIC STRUCTURE OF TiS3

A. S. Shkvarin1, Yu. M. Yarmoshenko1, M. V. Yablonskikh2, A. I. Merentsov1,3, A. N. Titov1,3
1Institute of Physics of Metals, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russia
2Sincritrone Trieste, SCp A, Basovizza I-34012, Italy
3Ural Federal University, Ekaterinburg, Russia
Keywords: resonant photoemission, photoelectron and absorption spectroscopy, titanium trisulfide

Abstract

X–ray photoemission and absorption spectra of TiS3 are studied. The temperature dependence of the magnetic susceptibility is measured and the electron density of states is calculated. Titanium ions in different oxidation states are found to coexist.