CRYSTAL STRUCTURES OF [MEn2][Pt(NO2)4] (M = Cu, Pd)
S. P. Khranenko1, N. V. Kuratieva1,2, S. A. Gromilov1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: palladium, copper, platinum, ethylenediamine, double complex salt, single crystal X-ray diffraction study, crystal chemistry
Abstract
By single crystal X-ray diffraction the structures of [CuEn2][Pt(NO2)4] and [PdEn2][Pt(NO2)4] are determined. In the structures, the main structural moieties are identified. It is shown that the structure of [PdEn2][Pt(NO2)4] can be considered as quasi-one-dimensional: in the Y axis direction, the stacks of alternating complex cations and anions locate.
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