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Chemistry for Sustainable Development

2014 year, number 2

Methane Chlorination on Fibreglass Catalysts

N. V. TESTOVA, E. A. PAUKSHTIS, V. B. GONCHAROV and V. N. PARMON
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia)
E-mail: testova@catalysis.ru
Keywords: fibreglass catalysts, methyl chloride, methane chlorination
Pages: 193–199

Abstract

Gas phase methane chlorination in the presence of fibreglass catalysts has been investigated. It has been demonstrated that increasing the acidity of the glass fibres leads to an increase in the selectivity of the formation of methyl chloride. Unlike zeolite catalysts, the fibreglass catalysts are stable and do not get deactivated during several dozens of hours.