CHARGE DISTRIBUTION AND MOBILITY OF LITHIUM IONS IN Li2TiO3 FROM 6,7Li NMR DATA
Ya. V. Baklanova1, I. Yu. Arapova2, I. R. Shein1, L. G. Maksimova1, K. N. Mikhalev2, T. A. Denisova1
1Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences
2Institute of Metal Physics, Ural Division, Russian Academy of Sciences
Keywords: lithium titanate, 6,7Li NMR, ion mobility, ab initio EFG calculations
Abstract
A comparative analysis of 6,7Li NMR spectra is performed for the samples of monoclinic lithium titanate obtained at different synthesis temperatures. In the 7Li NMR spectra three lines are found, which differ in quadrupole splitting frequencies νQ and according to ab initio EFG calculations are assigned to three crystallographic sites of lithium: Li1 (νQ ~ 27 kHz); Li2 (νQ ~ 59 kHz); Li3 (νQ ~ 6 kHz). The dynamics of lithium ions is studied in a wide temperature range from 300 K to 900 K. It is found that the narrowing of 7Li NMR spectra as a result of thermally activated diffusion of lithium ions in the low-temperature Li2TiO3 sample is observed at a higher temperature in comparison with a sample of high-temperature lithium titanate. Based on the analysis of 6Li NMR spectra it is assumed that there is mixed occupancy of lithium and titanium sites in the corresponding layers of the crystal structure of low-temperature lithium titanate, which hinders lithium ion transfer over regular crystallographic sites.
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