CRYSTAL STRUCTURE OF A TANTAL CLUSTER WITH TETRAPHENYLBORATE‑ANION: [Ta6Br12(H2O)6](BPh4)2·4H2O
V. Anyushin1,2, M. N. Sokolov1,2, E. V. Peresypkina1, V. P. Fedin1,2
1A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
caesar@niic.nsc.ru
2Novosibirsk State University
Keywords: tantalum, bromine, cluster, X-ray structure, hydrogen bonds
Abstract
The crystal structure of the [Ta6Br12(H2O)6](BPh4)2⋅4H2O salt (1), obtained from Ta6Br14⋅7H2O and NaBPh4, is determined by X-ray crystallographic analysis. The structure contains a network of hydrogen bonds, which organizes the cluster cations into layers.
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