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Chemistry for Sustainable Development

2013 year, number 2

Development of Resource-Saving Technologies in the Production of Organosilicon Enamels Basing on Rectification

M. N. KLEYMENOVA, L. F. KOMAROVA and YU. S. LAZUTKINA
Polzunov Altai State Technical University, Pr. Lenina 46, Barnaul 656099 (Russia)
htie@mail.ru
Keywords: distillation, resource–saving butanol–toluene mixture, liquid–liquid equilibrium, rectification analysis, chromatography, topological thermodynamic analysis, pentatope, schematic separation process diagram, azeotropic separating agent
Pages: 201–208

Abstract

A topological thermodynamic analysis was performed for a butanol–toluene mixture produced as a waste in the industry of paint–and–lacquer materials. Liquid–liquid equilibrium was experimentally studied in the system ethanol–toluene–chlorobenzene–water. Main pathways for separating a butanol–toluene mixture have been synthesized as flow graphs. A rectification analysis was performed for the system under study. Choosing a separating agent (benzene) has been performed. Variants were proposed for the technological schemes of the butanol–toluene mixture separation via combining simple and azeotropic distillation techniques.