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Chemistry for Sustainable Development

2013 year, number 2

Distribution of Polycyclic Aromatic Hydrocarbons in Natural Objects over the Territory of Scattering the Emissions from the Irkutsk Aluminum Plant (Shelekhov City, the Irkutsk Region)

I. I. MARINAYTE1, A. G. GORSHKOV1, E. N. TARANENKO2, E. V. CHIPANINA1 and T. V. KHODZHER1
1Limnological Institute, Siberian Branch of the Russian Academy of Sciences,Ul. Ulan-Batorskaya 3, Irkutsk 6640333 (Russia)
marin@lin.irk.ru
2Siberian Institute of Plant Physiology and Biochemistry, Siberian Branch of the Russian Academy of Sciences, Ul. Lermontova 132, Irkutsk 664032 (Russia)
Keywords: polycyclic aromatic hydrocarbons, snow cover, soil, pine and larch needles, water and bottom sediments, urban aerosol
Pages: 135–146

Abstract

Accumulation levels were determined for polycyclic aromatic hydrocarbons (PAHs) in naturally occurring objects over the territory of dispersing the emissions of the Irkutsk Aluminum Plant “IrkAZ–Sual”: in the snow cover, soil, pine needles (Pinus sylvestris L.) and larch needles (Larix sibirica), in water and the bottom sediments of the. Olkha River, as well as in the near-surface aerosols in Shelekhov City. An estimation was performed for the level of contamination with PAH compounds in the area of the Shelekhov City within the framework of the MPC and background levels, a conclusion has been drawn concerning the distribution of PAH emissions from the source over a limited area. Among the isolated fractions of PAHs, using a gas chromatography-mass spectrometry technique there have been identified and determined 14 arenes including those from the list of priority organic pollutants.