STRUCTURE OF THE COMPLEX OF HEXANUCLEAR MANGANESE PIVALATE WITH ISONICOTINAMIDE
E. Yu. Fursova, V. I. Ovcharenko, A. S. Bogomyakov, G. V. Romanenko
Keywords: Mn(II, III) complexes, polynuclear compounds, ditopic ligands, isonicotinamide, coordination polymers, X-ray crystallographic analysis
Abstract
The structure of the [Mn6(O)2(Piv)10L2]∞ compound, where Piv is the pivalate anion and L is isonicotinamide, is investigated. Its solid phase is found to be formed by polymeric layers within which hexanuclear fragments {Mn6(O)2(Piv)10} are bound by bidentate bridging L. The molecules of the solvent (Me2CO or EtOAc) in which the synthesis was performed are incorporated into the inter-layer space of the crystal.
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