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Journal of Structural Chemistry

2013 year, number 1

STRUCTURAL FEATURES OF THIOCARBAMIDE DERIVATIVES OF SOME LANTHANIDE IODIDES

T. A. Antonenko, L. Yu. Alikberova, D. V. Al’bov, N. S. Rukk
Keywords: lanthanide iodides, thiocarbamide, aquacomplexes, structure, synthesis

Abstract

Data on the synthesis, IR spectroscopy, and single crystal XRD are presented for thiocarbamide compounds of the composition [Ln(H2O)9]I3⋅2CS(NH2)2, where Ln = Dy (I) and Yb (II). The structural features of [Ln(H2O)9]I3⋅2CS(NH2)2 (Ln = Pr, Nd, Eu, Gd, Dy, Ho, Er, and Yb) are discussed. The compounds of thiocarbamide with Pr, Nd, Eu, Gd, and Dy iodides are found to form the first isostructural series characterized by a continuous network structure, while with Ho, Er, and Yb iodides the second isostructural series with a layered type structure is formed.