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Combustion, Explosion and Shock Waves

2013 year, number 1

Combustion of Furazanotetrazine Dioxide

V. P. Sinditskii, A. V. Burzhava, V. Yu. Egorshev, A. B. Sheremetev, V. P. Zelenov
Keywords: 1,2,5-oxadiazolo[34-e]-1, 2,3,4-tetrazine-4,6-dioxide, furazanotetrazine dioxide (FTDO), combustion rate, combustion mechanism, decomposition kinetics

Abstract

Combustion of furazanotetrazine dioxide (FTDO) was studied in a constant-pressure bomb in the range of pressures 0.1 ÷ 10 MPa. The thermal decomposition kinetics of FTDO in melt under non-isothermal conditions at temperatures 153 ÷ 179 °C was measured. The rate constants of the non-isothermal decomposition are described by an equation with an activation energy of 26.5 kcal/mol. It is concluded from the studies performed that the combustion of FTDO in the entire investigated pressure range obeys the gas-phase model, i.e., the leading combustion reaction is located in the flame.