SYNTHESIS AND SINGLE CRYSTAL X-RAY STRUCTURE OF 2,6-DI-TERT-BUTYL-4-(3-(4-CHLOROPHENYL)-4-METHYL-4,5DIHYDROISOXAZOL-5-YL)PHENOL 1,4-DIOXANE HEMISOLVATE
M. Rimaz1, J. Khalafy2, M. Badali2, K. Ељlepokura3, T. Lis3, A. Souldozi4, A. Ramazani5, S.W. Joo6
1Payame Noor University, Tehran, Iran 2Urmia University, Urmia, Iran 3University of WrocЕ‚aw, WrocЕ‚aw, Poland 4Islamic Azad University, Urmia, Iran 5Islamic Azad University, Zanjan, Iran aliramazani@gmail.com 6Yeungnan University, Gyeongsan 712-749, South Korea swjoo@yu.ac.kr
Keywords: single crystal X-ray structure, quinone methide, isoxazoline, oxime, DDQ
Abstract
The title compound (2,6-di- tert -butyl-4-(3-(4-chlorophenyl)-4-methyl-4,5-dihydroisoxazol-5-yl)phenol is synthesized and studied by the single crystal X-ray diffraction method. The structure of the product was confirmed by IR, 1H and 13C NMR spectroscopy. The crystal structure of 1,4-dioxane hemisolvate of the product is solved in the monoclinic space group P21/c with a = 17.713(6), b = 9.529(3), c = 13.972(4) Å, β = 94.09(4)°, V = 2352.3(13) Å3, Z = 4, T = 120(2) K.
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