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Journal of Structural Chemistry

2012 year, number 3

CRYSTAL AND MOLECULAR STRUCTURE OF THE COMPLEX OF N-(1-SILATRANYLMETHYL)-3,5-DIMETHYLPYRAZOLE WITH COBALT DICHLORIDE

M. G. Voronkov, Г‰. A. Zel'bst, A. D. Vasiliev, A. S. Soldatenko, Y. I. Bolgova, O. M. Trofimova
Keywords: N-(1-silatranylmethyl)-3, 5-dimethylpyrazole, cobalt dichloride, molecular structure, single crystal X-ray diffraction
Pages: 619-622

Abstract

X-ray diffraction is used to determine the crystal and molecular structure of the complex of N-(1-silatranylmethyl)-3,5-dimethylpyrazole with cobalt dichloride (I). This is yet another example of the participation of the endocyclic oxygen atom of the silatrane fragment in complexation with a metal atom. Metal dichloride interconnects two heterocyclic systems of dimethylpyrazole (DMP) and silatrane (Sa). The coordination polyhedron of the cobalt atom is a tetrahedron.