Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia



Advanced Search

Journal of Structural Chemistry

2012 year, number 3

COMPLEX SALTS WITH PARTICIPATION OF [Rh(NH3)6]3+ CATIONS

S. P. Khranenko, E. A. Bykova, A. V. Alexeyev, A. P. Tyutyunnik, S. A. Gromilov
Keywords: rhodium, rhenium, molybdenum, tungsten, complex salt, crystal chemistry, single crystal X-ray diffraction study
Pages: 527-533

Abstract

Four complex salts with the polyatomic [Rh(NH3)6]3+ cation are synthesized and studied by X-ray diffraction. The crystallographic characteristics of [Rh(NH3)6](WO4)Cl are determined and the structures of [Rh(NH3)6]Cl3, [Rh(NH3)6](ReO4)3·2H2O, and [Rh(NH3)6](MoO4)Cl·3H2O are solved. The features of mutual packing of the fragments are studied.