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Journal of Structural Chemistry

2012 year, number 2

STRUCTURE OF A FRAMEWORK COORDINATION POLYMER Zn2(dmf)(H2O)(atc)]·0.75DMF·0.5H2O

M. S. Zavakhina, D. G. Samsonenko, M. P. Yutkin, D. N. Dybtsev, V. P. Fedin
Keywords: zinc, adamantane tetracarboxylic acid, crystal structure, coordination polymers, metal-organic frameworks
Pages: 404-407

Abstract

In the interaction of Zn(NO3)2·6H2O and adamantane-1,3,5,7-tetracarboxylic acid (H4atc) in N,N′-dimethyl formamide (DMF) a three-dimensional coordination polymer with the composition [Zn2(dmf)(H2O)(atc)]·0.75DMF·0.5H2O (1) is produced. Its structure is determined by a single crystal X-ray diffraction study