Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia



Advanced Search

Journal of Structural Chemistry

2011 year, number 1

A TEMPERATURE STUDY OF ENAMINOIMINE TAUTOMERISM IN THE COCRYSTALS OF 3-(1-AMINO-2,2,2-TRIFLUOROETHYLIDENE)- 2-IMINO-1,1,4,5,6,7-HEXAFLUOROINDANE WITH DIOXANE BY SINGLE CRYSTAL XRD

T. V. Rybalova1, V. M. Karpov2, Y. V. Gatilov3
1
2
3
Keywords: temperature single crystal X-ray diffraction, polyfluorinated enaminoimines, indane, indene, tautomers, equilibrium
Pages: 218-222

Abstract

Single crystal X-ray diffraction is used to investigate the cocrystals of 3-(1-amino-2,2,2-trifluoroethylidene)-2-imino-1,1,4,5,6,7-hexafluoroindane (1) with 1,4-dioxane at temperatures of 100 K, 200 K, and 273 K. The study shows that compound 1 is in equilibrium with its tautomer: 2-amino-3-(1-imino-2,2,2-trifluoroethyl)-1,1,4,5,6,7-hexafluoroindene (1a).