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Journal of Structural Chemistry

2010 year, number 5

ADIABATIC AND ISOTHERMAL COMPRESSIBILITY OF AQUEOUS SOLUTIONS OF SODIUM CHLORIDE

A. A. Zaitsev, V. N. Afanasiev, A. N. Ustinov
Keywords: adiabatic compressibility, isothermal compressibility, aqueous solutions, hydration number
Pages: 916-926

Abstract

By the example of aqueous solutions of sodium chloride an approach is developed to obtain the hydration number, molar volume and compressibility of hydrate complexes using the data on adiabatic and isothermal compressibility. It is shown that the results of calculations based on isothermal and adiabatic compressibility are consistent with each other.