MIGRATION OF IMMISCIBLE HYDROCARBONS RECORDED IN CALCITE-HOSTED FLUID INCLUSIONS, ORDOS BASIN: A CASE STUDY FROM NORTHERN CHINA
Li Rongxia,b, Guzmics Tiborc, Liu Xioajiea,b, and Xie Guanchenga,b
aSchool of Earth Science and Resource, Chang'an University, Xian, 710054, China
bKey Laboratory of West Mineral Resource and Geology Engineering, Education Ministry of China, Chang'an University, Xian, 710054, China
cLithosphere Fluid Research Lab, Institute of Geography & Earth Sciences, Eötvös University Budapest (ELTE), Budapest, Hungary
Keywords: Hydrocarbon inclusion, boiling, oil migration, calcite veinlet, Ordos Basin
Pages: 1491-1503
Abstract
In this study one- (hydrocarbon liquid), two- (hydrocarbon liquid and vapor), and three- (hydrocarbon liquid and vapor, and aqueous liquid) phase fluid inclusions have been investigated in calcites occurring in veinlets in fine grained sandstones of Chang 7 source rock and Chang 8 reservoir rock. These rocks are parts of the Upper Triassic Yangchang Formation in the Ordos Basin, Northern China. The hydrocarbon inclusions studied show a high variance in vapor/liquid volume ratio at ambient temperature, suggesting a heterogeneous entrapment of vapor and liquid phases that existed before or during the formation of the calcite. This is supported by homogenization happened into both liquid and vapor phases. Homogenization temperatures range between 70 and 120?C. We assume that this wide range is the result of the heterogeneous entrapment of immiscible liquid and vapor phases rather than the high-temperature (e.g., 120 °C) formation of the hydrocarbon inclusions. Therefore, the lower range of homogenization temperatures (around 80 °C) seems to be probable for the formation of the hydrocarbon inclusions studied. Fluorescent microscopic results on the hydrocarbon inclusions show a bright yellow color for the oil. Fluorescence spectrum indices show that oil in the inclusions is quite mature, similarly to the oil extract from Chang 7 source rock. The differences in fluorescent spectra among the hydrocarbon inclusions suggest their chemical modification during evolution, which might be determined by continuous separation of vapor phase (gas condensate) from the system. On the basis of organic geochemistry of the studied samples (e.g., akin distribution of normal alkanes and similar isoprenoid ratios), it can be concluded that the oil in the inclusions and the crude oil from the Chang 8 reservoir rock are actually derived from the Chang 7 source rock. During the tectonic evolution, the hydrocarbon might undergo phase separation (boiling) yielding two phases (liquid and vapor) owing to the intense uplifting of the Ordos Basin after the Late Cretaceous. The boiling in the accumulated hydrocarbon could have resulted in overpressure in the source rock. This phenomenon might favor the formation of fractures and migration of hydrocarbons from their source toward sandstone reservoirs. Our study demonstrates the significance of detailed analytical investigation of hydrocarbon inclusions in correlation with their potential source rock.
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