Catalytic Processing Dimethyl Disulphide into Dimethyl Sulphide
A. V. MASHKINA
Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia) amash@catalysis.ru
Keywords: catalysts, dimethyl disulphide, dimethyl sulphide
Pages: 181–188
Abstract
Regularities were studied concerning dimethyl disulphide transformation in an atmosphere of helium in the presence of solid catalysts those differ from each other in the acid-base properties. The catalysts containing mainly BrØnsted acidic centres or strong basic centres on the surface exhibit a low activity level. Under the action of weak Lewis acidic centres, the dimethyl sulphide is formed at a low rate, however with increasing the strength of these centres the rate of dimethyl sulphide formation increases. For a catalyst to exhibit a high activity level in the formation of dimethyl sulphide, it is required for the presence of strong Lewis and BrØnsted centers, as well as basic centres with a moderate strength on the surface. The results of kinetic studies indicate that before 200 °C there is a parallel reaction scheme realized, whereas at a higher temperature the reaction scheme is consecutive. The reaction kinetic type varies from the first-order kinetics to zero-order one depending on the concentration of the substrate. The rate of dimethyl sulphide formation increases with increasing the temperature, the apparent activation energy amounts to (55±1) kJ/mol. The selectivity level of dimethyl sulphide formation in the case of complete conversion level of the substrate reaches 50–60 %.
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