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Chemistry for Sustainable Development

2012 year, number 1

Ion Conductors with the Conductivity over Lithium Ions and Solid Electrochemical Devices Based on Them

N. F. UVAROV1,2,3, A. S. ULIKHIN1 and YU. G. MATEISHINA1,3
1 Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences,
Ul. Kutateladze 18, Novosibirsk 630128 (Russia)
uvarov@solid.nsc.ru
2 Novosibirsk State Technolgoical University,
Pr. Marksa 20, Novosibrisk 630092 (Russia)
3 Novosibirsk State University,
Ul. Pirogova 2, Novosibirsk 630090 (Russia)
Keywords: solid electrolytes, lithium ionic conductors, solid batteries and rechargeable batteries, solid supercapacitors
Pages: 69–76

Abstract

A review of works aimed at the development of solid electrochemical devices based on lithium systems is presented. The criteria for the choice of solid electrolyte are described, a brief review of the properties of known solid electrolytes under in solid lithium batteries and rechargeable batteries are described. Special attention is paid to the properties of composite solid electrolytes. Examples of known solid primary and secondary lithium current sources differing in design and type of solid electrolyte are presented. It is shown that the composite solid electrolytes (ceramic, polymer ceramic and glass ceramic) are most suitable for use in solid lithium rechargeable batteries. A brief review of the works aimed at the development of solid supercapacitors is given. The data on solid supercapacitors with solid electrolyte based on lithium perchlorate and carbon electrode materials are presented.