1,3-Dipolar Cycloaddition of 4-Methoxybenzonitriloxide to О±,ОІ-Unsaturated Esters of О±-D-xylo-Pentadialdo-1,4-Furanose Series
N. A. Ermolaeva, I. P. Tsypysheva, S. L. Khursan, A. N. Lobov, I. P. Baykova, L. V. Spirikhin, M. S. Yunusov
Institute of Organic Chemistry, Ufa Scientific Centre of the Russian Academy of Sciences
tsipisheva@anrb.ru
Keywords: 1, 3-dipolar cycloaddition, nitriloxides, О±, ОІ-unsaturated esters, regioselectivity, asymmetric induction, diastereoselectivity
Pages: 485-491
Abstract
Regio- and diastereoselectivity of 1,3-dipolar cycloaddition of 4-methoxybenzonitriloxide to α,β-unsaturated esters of α-D-xylo-pentadialdo-1,4-furanose depending on the geometry of the double bond and the method of generation of nitriloxide is studied.
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