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Chemistry for Sustainable Development

2008 year, number 6

Controllable Ozonolysis of Alkenes

Victor Odinokov
Keywords: ozonolysis, controllable, alkenes, polyenes, cyclic, bicyclic, caoutchouc, pheromones, juvenoids, polyprenols, terpenoids, chlorophyll, phyton, О±-tocopherol, ecdysteroids, analogs
Pages: 739-745

Abstract

By means of controllable ozonolysis of acyclic, cyclic and bicyclic alkenes and polyenes of regular structure and given configuration through dosing the calculated amount of ozone, followed by controllable decomposition of the peroxide products of ozonolysis, polyfunctional aliphatic and heterocyclic compounds, α,ω-bifunctional unsaturated compounds of the required (Z)- or (E)-configuration were synthesized. The routes of transformations of ozonolysis products were proposed for the synthesis of insect pheromones, juvenoids, acyclic terpenoids, tocopherols, ecdysteroids and their analogs.